Chemistry, materials, & energy publications
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Thermochemistry of the Gaseous Vanadium Chlorides VCl, VCl2, VCl3, and VCl4
Gaseous equilibria in the V−Ag−Cl system were studied at elevated temperatures by effusion-beam mass spectrometry, where the pertinent species were generated by reaction of Cl2(g) with V + Ag granules…
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Step Formation on Hydrogen-Etched 6H-Sic{0 0 0 1} Surfaces
The formation of step bunches and/or facets on hydrogen-etched 6H-SiC(0 0 0 1) and (0001¯) surfaces has been studied, using both nominally on-axis and intentionally miscut (i.e. vicinal) substrates.
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Triple-Axis X-Ray Reciprocal Space Mapping of InyGa1−yAs Thermophotovoltaic Diodes Grown on (1 0 0) InP Substrates
Analysis of the composition, strain-relaxation, layer-tilt, and the crystalline quality of InyGa1−yAs/InP1−xAsx thermophotovoltaic (TPV) diodes grown by metal-organic vapor phase epitaxy (MOVPE) is demonstrated using triple-axis X-ray reciprocal space mapping techniques.
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Novel Enhancement of Thin-Form-Factor Galvanic Cells: Probing Halogenated Organic Oxidizers and Metal Anodes
The work reported herein demonstrates a novel method to improve the overall performance of thin-form-factor galvanic cells, fabricated via micro-electromechanical systems (MEMS) processes.
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Fuel 109-New Proton Conductive Composite Materials with Inorganic and Styrene Grafted and Sulfonated Vdf/Ctfe Fluoropolymers
To understand the effect of different membrane components on its properties, thermal properties of composites have been investigated. It was found that the content of CTFE units, St and sulfonic…
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Imaging Atom-Probe Studies of a Field Evaporation Based Deuterium Ion Source for Neutron Generators
Extended abstract of a paper presented at Microscopy and Microanalysis 2008 in Albuquerque, New Mexico, USA, August 3 – August 7, 2008
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Spatially Correlated Fluctuations and Coherence Dynamics in Photosynthesis
Here we present a generic model in which a strong intermolecular steric restoring force in densely packed pigment-protein complexes results in a spatial correlation in conformational (static) variations of chromophores,…
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Measurement of Debris in the Flow from Pyrotechnic Reactions Using an Instrumented Hopkinson Pressure Bar
When an NASA standard initiator (NSI) combusts within the confinement of a pyrovalve, debris is generated and entrained into flow. This debris can originate from the closure disc, the zirconium…
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Energetics of SixOyCz Polymer-Derived Ceramics Prepared Under Varying Conditions
In this work, we support earlier studies that the resistance to crystallization of these nanodomain networks is due to thermodynamic as well as kinetic factors.
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Synthesis of Two Potential Heterocyclic Amine Food Mutagens
The syntheses of two potential food mutagens formed during cooking, 2-amino-3,6,7-trimethyl-3H-imidazo[4,5-b]pyridine (1) and 2-amino-3,6,7-trimethyl-3H-imidazo[4,5-c]pyridine (2), are described.
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Nitric Oxide Production from Surface Recombination of Oxygen and Nitrogen Atoms
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Defect Reduction of GaAs/Si Epitaxy By Aspect Ratio Trapping
We report on the metallorganic chemical vapor deposition growth of GaAs on patterned Si (001) substrates, which utilizes the aspect ratio trapping method. It was found that when growingGaAs above the SiO2SiO2 trenched region, coalescence-induced…